期刊
EXPRESS POLYMER LETTERS
卷 13, 期 7, 页码 618-631出版社
BUDAPEST UNIV TECHNOL & ECON
DOI: 10.3144/expresspolymlett.2019.52
关键词
polymer synthesis; molecular engineering; thermosetting resins; recycling
资金
- New National Excellence Program of the Ministry of Human Capacities [UNKP 17-3-I]
The solvolysis of poly(ethylene-terephthalate) (PET) is one of the most researched areas in chemical recycling. In this study PET aminolysis with isophorondiamine has been done - in opposition to recent trends - without excess reagent and the raw reaction product was further used without purification. The aminolysis product was thoroughly characterized with nuclear magnetic resonance (NMR) spectroscopy. Isophoronediamine was used as a solvent to prepare amine cross-linker solutions for epoxy resins. The effect of the concentration on the cross-linking reaction and thermomechanical properties were investigated. The curing reaction was found to be significantly accelerated by the presence of the aminolysis product. Both the ethylene-glycol and the terephthal-amide-diamines have a catalytic effect on the reaction. The glass transition temperature decreased with increasing concentrations of the cross-linker solutions due to the decreasing cross-link density. Thus, raw aminolysis products can be utilized for epoxy curing and are advantageous in modifying slower curing cycloaliphatic cross linker systems.
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