期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 49, 页码 7025-7028出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02421b
关键词
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资金
- EPSRC [EP/K039547/1]
- University of Manchester
- Ramsay Memorial Trust
- EPSRC [EP/K039547/1] Funding Source: UKRI
We report an empirical correlation between the blocking temperature of large energy barrier SMMs and the relaxation time at the point where the Raman and Orbach relaxation mechanisms have the same rate; this supports the idea that the ability to retain magnetisation is controlled by the Raman relaxation process in these materials.
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