期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 48, 页码 6835-6837出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01337g
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资金
- U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (BES), Chemical Sciences, Geosciences, and Biosciences Division through its Geosciences program at Pacific Northwest National Laboratory (PNNL)
- U.S. Department of Energy Office of Fossil Energy at PNNL through the National Energy Technology Laboratory, Morgantown, West Virginia
- University of Wyoming (UW) Department of Geology and Geophysics
- University of Wyoming (UW) School of Energy Resources
- University of Wyoming School of Energy Resources
- Nielson Energy Fellowship
Magnesite (MgCO3) precipitation within the nanoconfined space of adsorbed H2O films (similar to 5 monolayers) was determined to have an apparent activation energy of only 36 +/- 6 kJ mol(-1), suggesting that Mg2+ under nanoconfinement adopts a hydration configuration that mimics that of aqueous Ca2+, at least energetically, if not also specifically in hydration structure.
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