期刊
RSC ADVANCES
卷 9, 期 29, 页码 16554-16564出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra02655j
关键词
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资金
- Ministry of Science and Higher Education, Poland [0215/DIA/2015/44]
- National Science Centre of Poland [ETIUDA 6 2018/28/T/ST5/00005, PRELUDIUM 12 2016/23/N/NZ7/00351]
- Wroclaw Centre for Networking and Supercomputing [18]
In this study, we newly designed and developed a synthesis route based on the 1,3-dipolar cycloaddition of the derivatives of 4 0 -(1,2,3-triazol-4-yl) phenyl-2,2 0 : 6 0,2 00 -terpyridine with various (hetero) aryl substituents, differing in electronic character, on a triazol ring. The obtained compounds were comprehensively characterized by UV-Vis spectroscopy and electrochemical and thermal studies. Moreover, preliminary biological tests were conducted. The investigation allowed the selection of materials with the most promising properties with particular emphasis on the nature of the substituents. In addition, theoretical studies (DFT and TD-DFT) were performed to verify the comprehensive understanding of experimental results.
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