期刊
MATERIALS TODAY CHEMISTRY
卷 12, 期 -, 页码 187-199出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.mtchem.2019.01.004
关键词
Nanoparticles; Fe-doped ZnO; Taguchi design; Photocatalyst; Methyl orange
In the current work, the Taguchi design of experiment and Grey relational analysis (GRA) was used to optimize various experimental parameters, such as mol% of Fe3+ doping, fuel, wt% of NH4Cl flux, calcination temperature for the preparation of Fe3+ -doped zinc oxide (FZO) by solution combustion synthesis. The powder X-ray diffraction pattern of FZO exhibits that crystallite size is increasing with increase in calcination temperature and the band gap was found to decrease with increase in mol% of Fe3+. The surface morphology of FZO nanoparticles (NPs) studied using a scanning electron microscope was found to be distinctive structures such as cubic shape, irregular mesoporous particles, tiny clusters, large and spongy pores structure and so on. High-resolution transmission electron microscopy images, selected area electron diffraction (SAED) pattern, and an energy-dispersive X-ray spectrum confirm the presence nanoscale FZO NPs, the polycrystalline nature and elemental composition. Various analyses, such as the signal-to-noise ratio ratio, analysis of variance (ANOVA) and GRA, were performed to validate the predicted optimal model. The ANOVA indicates that the crystallite size was significantly affected by calcination temperature with contribution factor 93.28%. Band gap energy was affected by both mol% of Fe3+ doping and calcination temperature with contribution 66.41% and 25.70%, respectively. Grey relational grading confirmed that the combination 5% doping, D-glucose fuel, 10% of flux and 600 degrees C calcination temperature can be used to get lower band gap energy (2.87 eV) and lower crystallite size (11.63 nm). Finally, Grey theory prediction helps us to choose a combination of 5% of doping, oxalic acid as a fuel, 5% of NH4CI flux and 500 degrees C calcination temperature to obtain the required band gap of 2.61 eV and the crystallite size 10.12 nm. The FZO NPs were used for photocatalytic degradation of methyl orange (MO) dye. The photocatalytic degradation results showed that the MO dye removal rate efficiency is higher (82.30%) on the Grey theory prediction result as compared with other L-9 orthogonal array. (C) 2019 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据