期刊
MATERIALS TODAY CHEMISTRY
卷 12, 期 -, 页码 178-186出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.mtchem.2019.01.002
关键词
Donor-Acceptor type; Fluorescence quenching; Sensor; Nitroaromatics
资金
- DST-RCUK [SR/RC-UK/APEX Phase II/2015]
- UKRI Global Challenge Research Fund project, SUNRISE [EP/P032591/1]
- DST under Clean Energy Research Initiative [DST/TMD/CERI/C140]
- Department of Science and Technology (DST), India, through the INSPIRE Faculty Award [IFA-13 ENG-57, DST/TM/WTI/2K16/23]
- Science and Engineering Research Board (SERB), Department of Science and Technology (DST) through NPDF [PDF/2017/001079]
- EPSRC [EP/P032591/1] Funding Source: UKRI
This work reports development of a new donor-acceptor-type star-shaped 4,4',4 ''-(1,3,5-triazine-2,4,6-triyl)tris(N,N-diphenylaniline) (TRZDPA) molecule towards detection of an ultratrace amount of picric acid (PA). TRZDPA showed solvent-dependent fluorescence spectra in an excited state owing to its strong intramolecular charge-transfer properties. As a fluorescent probe, TRZDPA shows remarkable sensitivity towards the PA in a highly selective manner compared with other nitroaromatic compounds. Furthermore, efficiency of the quenching process was evaluated by the Stern-Volmer equation. The fluorescence quenching mechanism of the probe during PA detection was evaluated from the photophysical and other spectral characterizations. The detection limit of PA was 0.37 nM, confirming the detection of PA in aqueous media at a trace level. To facilitate easy detection of PA, TRZDPA-modified fluorescent thin-layer chromatography (TLC) strips were developed as 'turn-off' sensors which can be visualized by the naked eye. (C) 2019 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据