期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 50, 页码 7151-7154出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01872g
关键词
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资金
- National Natural Science Foundation of China [21476232, 21607029, 21777033]
- International Partnership Program of Chinese Academy of Sciences [121421KYSB20170020]
- State Key Laboratory of Catalysis in the Dalian Institute of Chemical Physics [N-16-07]
- Science and Technology Program of Guangdong Province [2017B020216003]
- Science and Technology Program of Guangzhou City [201707010359]
- National Supercomputing Centre in Guangzhou (NSCCGZ)
- 1000 Plan Program for Young Professionals of China
- 100 Talents Program of Guangdong University of Technology
Herein, we, for the first time, report a high spin Co-Fe Prussian blue analogue (Co-Fe PBA) as a highly efficient Fenton-like catalyst for sulfate radical (SO4 center dot-) production. Our experiments and density functional theory (DFT) calculations show that the largely elongated SO4-OH bond length, strengthened adsorption and facilitated electron transfer for peroxymonosulfate (PMS) activation catalyzed by high-spin (HS) CoII are the main factors contributing to its excellent activity.
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