期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 49, 页码 7081-7084出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03201k
关键词
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资金
- Deakin University [DP160103046]
- Australian Research Council [DP160103046]
- Royal Society [IES\ R3\ 170367]
A new approach to examine electrochemiluminescence (ECL), in which the potentials at both the working and counter electrodes are measured and the emitted light is detected by a photomultiplier tube, camera and then a charge-coupled device (CCD) spectrometer, provides unequivocal evidence that the purported cathodic ECL of [Ru(bpy)(3)](2+) and tri-n-propylamine actually arises from anodic reactions at the counter electrode.
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