Synthesis of star-shaped small molecules carrying peripheral 1,8-naphthalimide functional groups and their applications in organic solar cells

A series of novel star-shaped small molecules with triphenylamine as the core, oligothiophene as the spacer and 1,8-naphthalimide as the electron withdrawing end-group were synthesized and used as donor materials for solution-processed organic solar cells. Direct arylation and Suzuki cross-coupling were used to synthesize the key intermediates and star-shaped molecules. The star-shaped molecules showed good thermal stability, intense absorption in the range of 300-700 nm, and deep HOMO energy level. A bulk heterojunction organic solar cell with one of the star shaped molecules in combination with PC71BM as the active layer gave a power conversion efficiency of 232% with a high open-circuit voltage up to, 0.94 V. The influence of the spacer between the triphenylamine core and the peripheral 1,8-naphthalimide function group on the optical and photovoltaic properties was also investigated. Our studies indicated that 1,8-naphthalimide can be used as a promising building block for the synthesis of novel donor materials for organic solar cells. (C) 2015 Elsevier Ltd. All rights reserved.