期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 9, 期 12, 页码 3020-3022出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cy00791a
关键词
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资金
- Western Washington University
- NSF [MRI: 1532269]
- ANR
A strategy for the conversion of terminal epoxides to primary alcohols is presented. The reaction uses hydrogen as the only stoichiometric reagent and is promoted by an iridium precatalyst under acidic conditions. Selectivity for the formation of a terminal alcohol over an internal alcohol is observed for both alkyl- and aryl-substituted terminal epoxides in isolated yields of up to 50% and 72% respectively.
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