期刊
RSC ADVANCES
卷 9, 期 31, 页码 18013-18017出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra03277k
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资金
- University of Antwerp (BOF)
- Hercules Foundation
The iron(iii)-catalyzed efficient strategy for the synthesis of alpha-substituted homoallylamines was accomplished via a cationic 2-aza-Cope rearrangement of aldimines, generated in situ by condensation of commercially available aldehydes and easily synthesizable 1,1-diphenylhomoallylamines. This reaction features a broad substrate scope with high yields and is conducted in an eco-friendly solvent, i.e. dimethyl carbonate.
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