4.6 Article

Lewis acidic FeCl3 promoted 2-aza-Cope rearrangement to afford α-substituted homoallylamines in dimethyl carbonate

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RSC ADVANCES
卷 9, 期 31, 页码 18013-18017

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra03277k

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  1. University of Antwerp (BOF)
  2. Hercules Foundation

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The iron(iii)-catalyzed efficient strategy for the synthesis of alpha-substituted homoallylamines was accomplished via a cationic 2-aza-Cope rearrangement of aldimines, generated in situ by condensation of commercially available aldehydes and easily synthesizable 1,1-diphenylhomoallylamines. This reaction features a broad substrate scope with high yields and is conducted in an eco-friendly solvent, i.e. dimethyl carbonate.

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