期刊
DALTON TRANSACTIONS
卷 48, 期 24, 页码 8911-8919出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt00871c
关键词
-
资金
- National Natural Science Foundation of China [21874064]
- Guangdong Provincial Natural Science Foundation of China [2018A030313456]
- One Belt One Road Incubation Project from Southern Medical University [YD2018N003]
A water-stable three-dimensional (3D) metal-organic framework (MOF) of {[Tb(Cmdcp)(H2O)(3)](2)(NO3)(2)center dot 5H(2)O}(n) (1, H(3)CmdcpBr = N-carboxymethyl-(3,5-dicarboxyl)pyridinium bromide) has been synthesized and characterized. MOF 1 is highly emissive, giving rise to green luminescence that can be quenched by Fe3+ due to the partial overlap of its excitation spectrum with the absorption spectrum of Fe3+. The subsequent introduction of ascorbic acid (AA) leads to the reduction of Fe3+ into Fe2+, accompanied by the near-entire recovery of MOF 1 emission. The density functional theory (DFT) calculation results support the proposed mechanism. Such a sensing cycle is further transferable to urine and serum samples with a satisfactory near-quantitative recovery, highlighting its good potential in biologically relevant applications.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据