期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 166, 期 10, 页码 A2215-A2220出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.1121910jes
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Lithium oxide (Li2O) is a highly relevant material for battery applications, and as a binary antifluorite compound of first-row elements, it is equally interesting for basic science. This work investigates the behavior of ionic and electronic charge carriers in Li2O. The predominantly ionic conductivity is shown to be well-explained by a defect chemical model based on Frenkel disorder, vacancy migration, and vacancy-dopant association. The enthalpies and entropies of these three processes are derived, and good agreement is seen to isostructural Li2S, SrF2, and BaF2. An upper bound is determined for the electronic conductivity of Li2O, which is very low. These results provide more reliable thermodynamic and kinetic parameters for future rigorous treatments of Li2O in batteries. For example, even under favorable doping conditions, the ionic conductivity of bulk crystalline Li2O (with no higher-dimensional defects or interfacial effects) is multiple orders of magnitude too slow to account for the resistance of typical solid-electrolyte interface (SEI) layers. (c) The Author(s) 2019. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.
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