期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 131, 期 1, 页码 89-93出版社
SPRINGER
DOI: 10.1007/s10973-017-6665-x
关键词
TNT; DNAN; Thermal hazard; Accelerating rate calorimeter
资金
- Technology Innovation Program of Beijing Institute of Technology of China [2017CX10003]
The thermal decomposition behaviors of 2,4,6-Trinitrotoluene (TNT) and 1-methoxy-2,4-dinitro-benzene (DNAN) were studied by using a NETSCH company accelerating rate calorimetry. Hazard indicators such as onset temperature, adiabatic temperature rise, initial self-heat temperature, maximum self-heating rate, and time-to-maximum temperature rise rate have been determined directly. The kinetic parameters, such as the activation energy (E-a) and the pre-exponential factor (A) were studied from the measured self-heating rate data by assuming order reaction.
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