期刊
DALTON TRANSACTIONS
卷 48, 期 19, 页码 6501-6512出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt04725a
关键词
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资金
- SERB, DST [ECR/2016/000108]
- DST-INSPIRE [IFA-14/CH-143]
- CIF
- Department of Chemistry, IIT-Guwahati
- CSIR
The construction of C?N bonds was achieved by the dehydrogenative coupling of alcohol and azide via aza-Wittig type reaction. The reaction is catalyzed by an acridine-derived ruthenium pincer complex and does not use any oxidant. The present protocol offers a wide substrate scope, including aliphatic, aryl or heteroaryl alcohol/azides. This expeditious protocol was successfully applied to construct a C?C bond directly from alcohol via dehydrogenative Wittig reaction. Furthermore, the synthesis of structurally important pyrrolo[1,4]benzodiazepine derivatives was also achieved by this methodology.
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