4.2 Article

CELLULOSE SHEETS MADE FROM MICRO/NANOFIBRILLATED FIBERS OF BAMBOO, JUTE AND EUCALYPTUS CELLULOSE PULPS

期刊

CELLULOSE CHEMISTRY AND TECHNOLOGY
卷 53, 期 3-4, 页码 291-305

出版社

EDITURA ACAD ROMANE

关键词

natural fiber; cellulose nanofibril; mechanical defibrillation process; nanofibril characterization

资金

  1. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) [bex 14459/13-2]
  2. Conselho Nacional de Pesquisa e Desenvolvimento (CNPq) [309796/2012-1, 484082/2013-2, 506506/2013-4]
  3. Fundacao de Apoio a Pesquisa do Estado de Minas Gerais (Fapemig), Brazil [apq-02515-14]
  4. University of Toronto, Canada
  5. United States Department of Agriculture (USDA), USA

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The aim of this study was to investigate the properties of cellulose sheets made from fibrillated micro/nanofibrils of bamboo, jute and eucalyptus. Micro/nanofibrils obtained from alkaline-treated jute had higher crystalline fraction (CF) and crystallinity index (CI). The onset degradation temperature (T-onset) was very similar for all the micro/nanofibrils (from 316 degrees C to 323 degrees C). Defibrillated cellulose nanofibrils had an average diameter in the range of 30-50 nm. Cellulose sheets made of bamboo and jute micro/nanofibrils had higher bending strength, elastic modulus and energy to break than the sheets made of eucalyptus micro/nanofibrils. Compared to the bamboo and jute samples, the eucalyptus micro/nanofibril suspension had a greater amount of fiber debris, which may have contributed to higher apparent porosity, water adsorption and water solubility of the cellulose sheets. Further development of the mechanical defibrillation process could lower the production costs of micro/nanofibrils and improve the performance of engineered cellulose-based materials.

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