期刊
CHEMICAL SCIENCE
卷 10, 期 25, 页码 6316-6321出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc00603f
关键词
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资金
- National Natural Science Foundation of China [21690063]
- National Basic Research Program of China [2015CB856600]
A Ru(ii)-catalyzed direct access to various functionalized allenoic acids via C-H allenylation of readily available aryl carboxylic acids with propargylic acetates is reported. Axially chiral allenoic acids could be obtained in high ee by using optically active propargylic acetates through a chirality transfer strategy.
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