期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 21, 期 19, 页码 9905-9911出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cp01243e
关键词
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资金
- National Key R&D Program of China [2016YFB0400702]
- National Science Fund of China [51525304, 61890942]
Here, we formulate a theoretical transport model for disordered organic semiconductors based on the concept of competitive hopping. We demonstrate theoretically that carriers occupying states with higher energy levels have higher probabilities and higher rates of hopping to the transport energy. This model suggests a temperature (T) dependence of mobility (mu) given by lg(mu) proportional to T-n, where the low carrier density and small energetic disorder limitation of the competitive hopping model gives the nonArrhenius lg(mu) proportional to T-2 relation, and the high carrier density and large energetic disorder limitation gives the Arrhenius type lg(mu) proportional to T-1 relation. The carrier density dependence of carrier mobility is steeper at high carrier density than at low carrier density. These results are well explained by the relative positions of the Fermi level and the equilibrium level as the initial hopping levels. The competitive hopping model successfully explains the trap energy dependence of the carrier mobility for systems with deep traps. The mobility enhancement with increasing trap energy at deep trapping situations can be explained by the increasing contribution to the carrier transport of the hopping between the intrinsic states.
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