期刊
ACS APPLIED BIO MATERIALS
卷 2, 期 7, 页码 2802-2811出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsabm.9b00226
关键词
amide-imine conjugate; oxovanadium(V); dioxomolybdenum; Cu(II) complex; (bio)catalysis; anticancer activity
资金
- CSIR (New Delhi)
- Department of Science & Technology (New Delhi) [PDF/2016/000160]
- DST-SERB, New Delhi, India [EEQ/2017/0076]
- FCT/MCTES [UID/CTM/50011/2019]
- national funds through the FCT/MCTES
An amide-imine conjugate, (E)-N'-((2-hydroxynaphthalen-1-yl) methylene)-4-methylbenzohydrazide (PTANAP), derived from 4-methyl-benzoic acid hydrazide (PTA) and 2-hydroxynapthaldehyde, is explored to prepare dinuclear oxovanadium(V), mononuclear dioxomolydenum(VI), and Cu(II) complexes. Single crystal X-ray structurally characterized complexes have been exploited as catalyst for oxidation of ethylbenzene, catechol, and o-aminophenol. The anticancer properties of the oxo-vanadium complex have been explored against human leukemia cell (K-562) and mouse lymphoma cells (2PK3).
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