期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 54, 页码 7828-7831出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03668g
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资金
- Natural Science Foundation of Jiangsu Province, China [BK20161191]
- National Natural Science Foundation of China [21476031, 21673024]
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center of Jiangsu Province
- project of Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology
Uniform ruthenium phosphide (Ru2P and RuP) nanocrystals grown in situ on N- and P-codoped graphene were obtained by pyrolyzing tris(triphenylphosphine) ruthenium(ii) chloride (TPP-Ru) with pyritic acid (PA). Interestingly, Ru2P and RuP can be controllably prepared by varying the molar ratio of PA to TPP-Ru. As an efficient electrocatalyst for the hydrogen evolution reaction (HER), Ru2P exhibited a better performance than RuP in alkaline medium.
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