期刊
CHEMICAL SCIENCE
卷 10, 期 26, 页码 6560-6564出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc01703h
关键词
-
资金
- Alexander von Humboldt Foundation
- WWU Munster (Graduate School of Molecules and Interfaces)
- Deutsche Forschungsgemeinschaft (Leibniz Award)
Herein we describe an unprecedented Ru-II-catalyzed site-selective and regiospecific annulation of benzoic acids with propargylic carbonates. The weakly coordinating carboxylic acid moiety outperformed other typically used directing groups in C-H activation, including ketone, nitrile, sulfonamide, amide and strongly coordinating nitrogen heterocycles. This is an important step towards the application of C-H activation reactions in complex (functional) real-world molecules.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据