期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 9, 期 13, 页码 3548-3553出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cy00951e
关键词
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资金
- Qatar National Research Fund, a member of Qatar foundation, Qatar [NPRP9-212-1-042, NPRP8-235-1-055]
- BMWi (project MethaCycle) [03ET6071A]
- State of Mecklenburg-Vorpommern, Germany
- analytical department of LIKAT
Reduction of various organic carbonates to methanol and alcohols can be achieved in the presence of a molecularly-defined homogeneous cobalt catalyst. Specifically, the use of Co(BF4)(2) in combination with either commercial or tailor-made tridentate phosphine ligands allows for additive-free hydrogenations of carbonates. Optimal results are obtained at relatively mild conditions (120 degrees C, 50 bar hydrogen pressure) in the presence of xylyl-Triphos L4.
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