期刊
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
卷 15, 期 1, 页码 141-152出版社
SPRINGER
DOI: 10.1007/s13738-017-1217-7
关键词
Quaternized polyvinyl alcohol; Quaternary ammonium groups; In situ polymerization; Adsorption isotherm
资金
- Scientific Research Fund of Liaoning Provincial Education Department [L2013153]
- Fundamental Research Funds for the Doctoral of Liaoning Provincial Natural Science Foundation [20141126]
- Science and Technology Development Fund Project of Fushun city [20141115]
- Fundamental Research Funds for the Doctoral of Liaoning Shi Hua University of China [2013XJJ-006]
An alkaline membrane with full interpenetrating network (Full-IPN) with positive charge groups of uniform distribution was prepared as adsorbent for removal of Rhodamine B (RB) and Congo red (CR) in single and binary dye systems. Compared with single dye system, in binary dye systems a synergistic effect is due to the interaction between RB (cationic dyes) and CR (anionic dyes), which will impede the adsorption of CR or RB. Moreover, under the same experimental conditions, the magnitude of CR removal is better than that of RB in binary dye systems and that in the single system. The aforementioned phenomenon has resulted from one CR molecule bound to one RB molecule; the RB-CR binding occurred spontaneously, and the main binding forces between CR and RB were hydrogen bond and van der Waals interactions. Pseudo-second-order rate equation and Freundlich adsorption isotherm are with the better fit in single and binary dye systems for fitting the kinetic data. The results of Delta G, Delta H and Delta S revealed that the adsorption process for single and binary systems is endothermic and spontaneous. The electrostatic interaction between the dye and the quaternized ammonium groups present in membrane was identified as a major mechanism of the adsorption process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据