期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 164, 期 7, 页码 A1773-A1783出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0131709jes
关键词
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资金
- Bavarian Ministry of Economic Affairs and Media, Energy, and Technology under EEBatt project
- BASF SE
A key for the interpretation of porous lithium ion battery electrode impedance spectra is a meaningful and physically motivated equivalent-circuit model. In this work we present a novel approach, utilizing a general transmission line equivalent-circuit model to exemplarily analyze the impedance of a porous high-voltage LiNi0.5Mn1.5O4 (LNMO) cathode. It is based on a LNMO/graphite full-cell setup equipped with a gold wire micro-reference electrode (GWRE) to obtain impedance spectra in both, non-blocking conditions at a potential of 4.4 V cell voltage and in blocking configuration achieved at 4.9 V cell voltage. A simultaneous fitting of both spectra enables the deconvolution of physical effects to quantify over the course of 85 cycles at 40 degrees C: a) the true charge transfer resistance (R-CT), b) the pore resistance (R-Pore), and c) the contact resistance (R-Cont.). We demonstrate that the charge transfer resistance would be overestimated significantly, if the spectra are fitted with a conventionally used simplified R/Q equivalent-circuit compared to our full transmission line analysis. (C) The Author(s) 2017. Published by ECS. All rights reserved.
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