期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 164, 期 9, 页码 A2262-A2267出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0371712jes
关键词
-
资金
- National Natural Science Foundation of China [21673222]
The electrochemical manner of hexafluorophosphate anion into a graphite electrode has been studied in mixed solvents of propylene carbonate (PC) and ethylmethyl carbonate (EMC). The successful electrochemical intercalation of PF6- has been gained in PC/EMC-based electrolyte solutions and the effect of PC and EMC on PF6- insertion into graphite in these electrolyte solutions has been studied by electrochemical tests, ex situ XRD and in situ Raman. Moreover, the interaction between anions and solvents in electrolyte solutions was investigated by nuclear magnetic resonance. Furthermore, Li/graphite cells based on these solutions cycled well. (C) 2017 The Electrochemical Society. All rights reserved.
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