期刊
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
卷 28, 期 9, 页码 1788-1802出版社
SOC BRASILEIRA QUIMICA
DOI: 10.21577/0103-5053.20170040
关键词
photocatalyst; sol-gel method; N-doped TiO2; UV-ABC irradiation; visible-light activity
资金
- Brazilian funding agency CNPq [486342/2013-1, 311798/2014-4]
- Brazilian funding agency CAPES
- Brazilian funding agency FUNDECT [23/200.247/2014]
This article reports the synthesis and characterization of pure and N-, B-, and Ag-doped TiO2 and the ability of these oxides to photodegrade methylene blue (MB) under sunlight or UV-ABC radiation. The compounds were synthesized using the sol-gel method and characterized by scanning electron microscopy, X-ray diffraction, diffuse reflectance spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. Photocatalytic efficiency was significantly increased by N- doping, resulting in 98% MB decomposition under UV-ABC irradiation for 180 min. Ag- and B- doped TiO2 lowered MB degradation rates to 52 and 73%, respectively, compared with pure TiO2. The same behavior was observed with exposure to UV- Vis, with 88, 65, 60, and 42% MB removal with N- doped, pure, B- doped, and Ag- doped TiO2, respectively. Under visible light alone, N- doped TiO2 exhibited higher photocatalytic efficiency than commercial P25-type TiO2. Photocatalysis with N- doped TiO2 proved to be a promising alternative for MB degradation, given the potential of employing solar energy, thus minimizing operating costs.
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