期刊
GREEN CHEMISTRY
卷 21, 期 14, 页码 3858-3863出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc01175g
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资金
- Hunan University of Science and Engineering and Hunan Provincial Natural Science Foundation of China [2019JJ20008]
The first example of visible-light-induced deoxygenative C2-sulfonylation of quinoline N-oxides with sulfinic acids in the presence of an organic dye as the catalyst was developed. The reaction conditions are eco-friendly and mild, employing ambient air as the sole oxidant and aqueous acetone solution as the solvent. This approach requires only a very low catalyst loading, allowing gram-scale preparation as well as late-stage modification of biologically active compounds bearing quinoline groups.
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