Dysprosium complexes bearing unsupported DyIII-GeII/SnII metal-metal bonds as single-ion magnets

Two dysprosium complexes bearing unsupported Dy-Ge/Sn metal-metal bonds are reported here, wherein the Dy-Ge and Dy-Sn bonds both contain relatively large covalency. The complexes exhibit slow relaxation of magnetization at zero field with energy barriers of 485 and 620 K, respectively, and the blocking temperature of 6 K.