期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 9, 期 14, 页码 3647-3655出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cy00562e
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资金
- Japan Society for the Promotion of Science [17K18123]
- Promotion and Mutual Aid Corporation for Private Schools of Japan [Science Research Promotion Fund]
- Tokai University Supporters [Association Research and Study Grant]
- Grants-in-Aid for Scientific Research [17K18123] Funding Source: KAKEN
Monoamino cyclic tellurides with a five-or six-membered ring structure and their derivatives were developed as a new class of catalyst for the oxidation of organothiols to organodisulfides in a glutathione peroxidase-like catalytic reaction. Quantitative conversion and high reaction rate were achieved by performing the reaction in an organic-aqueous segmented microflow system. Importantly, the process circumvented product purification, which is a major limitation of current organodisulfide synthetic methods.
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