期刊
RSC ADVANCES
卷 9, 期 37, 页码 21311-21317出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra02942g
关键词
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资金
- ACCEL, Japan Science and Technology Agency (JST) [JPMJAC1501]
- Ministry of Education, Culture, Sports, Science and Technology of Japan [18K04868]
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2018R1A6A3A03012052]
- National Research Foundation of Korea [2018R1A6A3A03012052] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- Grants-in-Aid for Scientific Research [18K04868] Funding Source: KAKEN
We investigated the relationship between crystalline disorder and electronic structure deviations of Pd nanoparticles (NPs) and their hydrogen storage properties as a function of their particle diameter (2.0, 4.6 and 7.6 nm) using various synchrotron techniques. The lattice constant of the 2.0 nm-diameter Pd NPs was observed to be larger than that of the 4.6 or 7.6 nm-diameter Pd NPs. With increasing particle diameter the structural ordering was improved, the lattice constant and atomic displacement were reduced and the coordination numbers increased, as determined using high-energy X-ray diffraction, reverse Monte Carlo modelling and X-ray absorption fine structure spectroscopy. The structural order of the core part of the larger NPs was also better than that of the smaller NPs. In addition, the bond strength of the Pd-H formation increased with increasing particle diameter. Finally, the surface order of the Pd NPs was related to enhancement of the hydrogen storage capacity and Pd-H bond strength.
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