期刊
AUSTRALIAN JOURNAL OF CHEMISTRY
卷 72, 期 7, 页码 524-532出版社
CSIRO PUBLISHING
DOI: 10.1071/CH19046
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资金
- VIT Chennai
- DST New Delhi [SB/FT/CS-068/2014]
Functionalized tetrahydroisoquinolines are convenient precursors for the construction of numerous heterocyclic compounds of therapeutic importance. In this paper we have illustrated an efficient synthesis of highly substituted tetrahydroisoquinolines from 2H-pyran-2-ones via nucleophile-mediated ring transformation with tert-butyl-4-oxopiperidine-1-carboxylate followed by acid-mediated cleavage of the tert-butyloxycarbonyl group. The products were achieved smoothly in high yields with flexibility of various substituents.
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