期刊
CHEMICAL SCIENCE
卷 10, 期 28, 页码 6863-6867出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc02341k
关键词
-
资金
- Natural Science Foundation of China [21572118]
- Tang scholar award
- Fundamental Research Funds of Shandong University
A rhodium-catalyzed highly regio- and enantioselective hydroalkynylation, generating cis-hydrobenzofuranone-tethered enynes has been developed. The reaction proceeds with a selective head-to-head insertion and symmetry breaking Michael addition cascade. One product was produced from tens of possible isomers through precise control of chemo-, regio-, and stereoselectivities using a single rhodium catalyst. Notable features of this method include 100% atom-economy, mild reaction conditions and a very broad substrate scope.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据