期刊
RSC ADVANCES
卷 9, 期 39, 页码 22343-22347出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra04770k
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资金
- AIST
- National Natural Science Foundation of China [21703061]
- Natural Science Foundation of Hunan province [2017JJ3081]
For the first time, by using H3PO3/I-2 system, various benzyl chlorides, bromides and iodides were dehalogenated successfully. In the presence of H3PO3, benzyl halides underwent electrophilic substitution reactions with electron-rich arenes, leading to a broad range of diarylmethanes in good yields. These transformations feature green, cheap reducing reagents and metal-free conditions. A possible mechanism was proposed.
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