期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 60, 页码 8848-8851出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03459e
关键词
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资金
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- 1000-Youth Talents Plan
- NSF of China [21690074, 21871288, 91856111, 21821002]
- innovative research team of the Ministry of Education
- innovative research team in SYPHU by the supporting fund for universities from the Chinese Central Government [51150039]
An unprecedented base-catalysed reductive relay hydroboration of allylic alcohols is described. Commercially available (BuLi)-Bu-n was found to be a robust transition metal-free initiator for this protocol, affording various boronic esters in high yield and selectivity. Mechanistically, this methodology involves a one-pot three-step successive process (dehydrocoupling/allylic hydride substitution/anti-Markovnikov hydroboration).
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