期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 60, 页码 8784-8787出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01851d
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资金
- INSA Rouen
- Rouen University
- CNRS
- EFRD
- Labex SynOrg [ANR-11-LABX-0029]
- Region Normandie (Crunch Network)
- IUF (Institut Universitaire de France)
- European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program [758710]
- UMR 6014 COBRA
- China Scholarship Council (CSC)
A transition metal-free approach was developed for the direct difunctionalization of disubstituted alkynes and terminal alkenes with concomitant formation of C-SCF2PO(OEt)(2) and C-Cl bonds. The BiCl3-mediated reaction offered access to high value-added functionalized scaffolds in a single operation under mild conditions. Extension to SCF2PO(OEt)(2)-containing alkynes was also studied.
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