期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 60, 页码 8844-8847出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03331a
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资金
- Wallenberg Foundation [KAW2016.0153]
- ERC [714737]
- European Research Council (ERC) [714737] Funding Source: European Research Council (ERC)
The oxidative rearrangement of 1,3-diketones is an underexplored alternative to enolate chemistry in the synthesis of all-carbon quaternary carboxylates. The mechanistic investigation of this reaction has resulted in a mild base mediated protocol, whose regioselectivity has been studied in challenging acyclic substrates.
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