期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 61, 页码 9007-9010出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04027g
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We herein report the gold(iii)-catalyzed selective annulation of anthranils with N-allylynamides under mild conditions. By trapping the in situ-generated alpha-imino gold carbenes, 3-azabicyclo[3.1.0]hexan-2-imines were obtained in high synthetic efficiency. The reaction, which can be conducted in the gram scale, tolerates electron-rich and electron-deficient anthranils as well as a diverse set of functionalized ynamides (aryl- and alkyl-substituted terminal).
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