期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 49, 页码 17763-17766出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b11127
关键词
-
资金
- JSPS [KAKENHI 17H01191, 17K19128, KAKENHI 16J09602]
- Asahi Glass Foundation
- JST [CREST 14529307]
- Grants-in-Aid for Scientific Research [17K19128, 16J09602, 17H01191] Funding Source: KAKEN
Aluminabenzene-rhodium and -iridium complexes were synthesized, in which the aluminum atom played as a proximal Lewis acidic site. Based on their structural analysis, aluminabenzene ligand could coordinate to Rh and Ir as a eta(5)-pentadienyl ligand. The Lewis acidic character of aluminum atom in aluminabenzene ligand was confirmed by treatment with 4-dimethylami-nopyridine to form the corresponding Lewis acid-base complexes. In addition, the alpha-selective C-H borylation of triethylamine with the aluminabenzene-ligated iridium catalyst was demonstrated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据