期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 19, 页码 6578-6581出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b02983
关键词
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资金
- ERC
- DFG [MA-4861/4-1, MA-4861/4-2]
- Austrian Academy of Sciences
A suite of flexible and chemoselective methods for the transition-metal-free oxidation of amides to alpha-keto amides and alpha-hydroxy amides is presented. These highly valuable motifs are accessed in good to excellent yields and stereoselectivities with high functional group tolerance. The utility of the method is showcased by the formal synthesis of a potent histone deacetylase inhibitor.
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