期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 39, 页码 13608-13611出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b07234
关键词
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资金
- Army Research Office [W911NF-17-1-0174]
- Center for Excitonics, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences [DE-SC0001088]
- U.S. Department of Energy
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357, DE-AC02-76SF00515]
- Office of Science, OBES, Division of Chemical Sciences, Geosciences, and Biosciences (CSGB) of the DOE [DE-AC02-05CH11231]
- National Science Foundation under NSF [ECS-0335765]
- National Science Foundation [ACI-1053575]
The two-dimensionally connected metal organic frameworks (MOFs) Ni-3(HIB)(2) and Cu-3(HIB)(2) (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both materials the Fermi energy lies in a partially filled delocalized band. Together with additional structural characterization and microscopy data, these results represent the first report of metallic behavior and permanent porosity coexisting within a metal organic framework.
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