期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 8, 页码 2855-2863出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b11259
关键词
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资金
- National Science Foundation [CHE-1359906]
- Office of Basic Energy Sciences, Department of Energy [DE-FG02-08ER46519]
- Ruhr University Research School PLUS by Germany's Excellence Initiative (DFG) [GSC 98/3]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1359906] Funding Source: National Science Foundation
Metal organic frameworks (MOFs) have rapidly grown into a major area of chemical research over the last two decades. MOFs represent the development of covalent chemistry beyond the molecule and into extended structures. MOFs also present an unprecedented scaffold for performing heterogeneous organic transformations in the solid state, allowing for deliberate and precise preparation of new materials. The development of these transformations has given rise to the postsynthetic renaissance, a suite of methods by which these materials can be transformed in a single-crystal-to-single-crystal manner. Postsynthetic modification, postsynthetic deprotection, postsynthetic exchange, postsynthetic insertion, and postsynthetic polymerization have exploited the unique features of both the organic and inorganic components of MOFs to create crystalline, porous solids of unique complexity and functionality.
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