期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 4, 页码 1428-1431出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b12443
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资金
- Deutsche Forschungsgemeinschaft [Al 1348/5-1]
The use of alpha-cationic phosphonites derived from TADDOL as ancillary ligands has allowed a highly regio- and enantioselective synthesis of substituted [6]-carbohelicenes by sequential Au-catalyzed intramolecular hydroarylation of diynes. Key for these results is the modular structure of these new ligands, and the enhanced reactivity that they impart to Au(I)-centers after coordination.
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