期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 16, 页码 5700-5703出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01922
关键词
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资金
- University of New Mexico (UNM)
- National Science Foundation [NSF CHE-1554299]
- NSF [CHE08-40523, CHE09-46690]
- NSF CRIF:MU award [CHE04-43580]
We present a strategy that difunctionalizes unactivated olefins in 1,2-positions with two carbon-based entities. This method utilizes alkyl/arylzinc reagents derived from olefin-tethered alkyl/aryl halides that undergo radical cyclization to generate C(sp(3))-Cu complexes in situ, which are intercepted with aryl and heteroaryl iodides. A variety of (arylmethyl)carbo- and heterocycles (N, O) can be synthesized with this new method.
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