期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 44, 页码 15580-15583出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b08575
关键词
-
资金
- NSF [CHE-1665125]
- University of North Carolina
Catalytic enantioselective addition of N-heteroarenes to terminal and internal 1,3-dienes is reported. Reactions are promoted by 5 mol % of Rh catalyst supported by a new chiral pincer carbodicarbene ligand that delivers allylic substituted arenes in up to 95% yield and up to 98:2 er. Mechanistic and X-ray evidence is presented that supports that the reaction proceeds via a Rh(III)-eta(3-)allyl.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据