期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 24, 页码 8082-8085出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b02856
关键词
-
资金
- ETH Zurich
- Swiss National Science Foundation [200020_152898]
- Swiss National Science Foundation (SNF) [200020_152898] Funding Source: Swiss National Science Foundation (SNF)
Iridium-(P, olefin) complex-catalyzed enantio- and diastereoselective formation of substituted spiroketals from racemic, allylic carbonates is reported, which enables the installation of multiple stereogenic centers in a single operation. The protocol was effective for the preparation of a collection of spiroketals of various ring sizes and substituents, including heteroatoms with high enantio- and diastereoselectivity. Furthermore, cascade reactions that couple this enantio- and diastereoselective transformation to additional reversible processes have been achieved to exert concomitant stereocontrol over additional stereogenic centers.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据