期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 14, 页码 5027-5030出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01774
关键词
-
资金
- NIH [GM-118641]
Palladium-catalyzed conjunctive cross-coupling is used for the synthesis of enantioenriched allylboron reagents. This reaction employs nonsymmetric bis(alkenyl)borates as substrates and appears to occur by a mechanism that involves selective activation of the less substituted alkene followed by migration of the more substituted alkene during the course of a Pd-induced metalate rearrangement.
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