期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 6, 页码 2145-2150出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b10352
关键词
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资金
- National Research Foundation
- Department of Science and Technology (SARCHI Program)
- Claude Leon Foundation
A soft porous Zn(II)-MOF (1) displays distinctive three-step hysteretic breathing behavior under ethane gas pressure at ambient temperatures. In situ single-crystal X-ray diffraction analysis was carried out at 298 K using an environmental gas cell in order to elucidate the different porous forms of the breathing framework under ethane gas. The three different phases were further characterized by pressure-gradient differential scanning calorimetry and variable pressure powder X-ray diffraction analysis.
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