期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 9, 页码 3344-3347出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b13389
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资金
- Scripps Research Institute
- NIH (NIGMS) [2R01GM084019]
Pd(II)-catalyzed enantioselective borylation of C(sp(3))-H bonds has been realized for the first time using chiral acetyl-protected aminomethyl oxazoline ligands. This reaction is compatible with carbocyclic amides containing alpha-tertiary as well as alpha-quaternary carbon centers. The chiral beta-borylated amides are useful synthons for the synthesis of chiral beta-hydroxylated, eta-fluorinated, and beta-arylated carboxylic acids.
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