期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 24, 页码 8114-8117出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04374
关键词
-
资金
- Robert A. Welch Foundation [F-0038]
- NIH-NIGMS [RO1-GM069445]
Using an iridium catalyst modified by PhanePhos, CF3-allenes react with methanol to form branched products of hydrohydroxymethylation as single regioisomers with excellent levels of enantiomeric enrichment. This hydrogen autotransfer process enables catalytic enantioselective formation of acyclic CF3-bearing all carbon quaternary stereocenters in the absence of stoichiometric metals or byproducts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据