期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 50, 页码 18146-18149出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b09989
关键词
-
资金
- JSPS KAKENHI [JP15K13634]
- MEXT KAKENHI [JP24109004]
- Grants-in-Aid for Scientific Research [15K13634] Funding Source: KAKEN
The push-pull effect has been widely used to effectively tune pi-electron systems. Herein, we report the synthesis and properties of 1-amino-2-boryldisilene 1 as the first push-pull disilene. Its spectroscopic and structural features show substantial interactions between the Si = Si double bond and the amino and boryl substituents. The pi -> pi* absorption band of 1 is remarkably red-shifted compared to that of the corresponding alkyl-substituted disilene 2. Treatment of 1 with H-2 resulted in the cleavage of two molecules of H-2 under concomitant formation of the corresponding trihydridodisilane and hydroborane.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据